Download Advances in catalysis by W G Frankenburg; V I Komarewsky; Eric K Rideal PDF

By W G Frankenburg; V I Komarewsky; Eric K Rideal

ISBN-10: 0080565077

ISBN-13: 9780080565071

ADVANCES IN CATALYSIS quantity 3.

content material: entrance disguise; Advances in Catalysis and similar topics, quantity III; Copyright web page; Contents; participants to quantity III; Editors' Preface; bankruptcy 1. Balandin's Contribution to Heterogeneous Catalysis; I. creation; II. The Multiplet concept; III. dialogue of the idea; IV. Steric issues in Catalysis; References; bankruptcy 2. Magnetism and the constitution of Catalytically lively Solids; I. creation; II. common rules; III. Experimental equipment; IV. The Susceptibility Isotherm; V. Supported Chromium Oxide; VI. Supported Oxides of Manganese; VII. Supported Nickel Oxide VIII. Supported Iron OxideIX. Supported Copper Oxide; X. similar structures; XI. Self-Supported platforms; XII. Ferromagnetism; XIII. identity of Ferromagnetic stages; XIV. response tactics; XV. resolution methods; XVI. precis; References; bankruptcy three. Catalytic Oxidation of Acetylene in Air for Oxygen Manufacture; I. creation; II. of Air and Acetylene; III. Acetylene removing; IV. Catalyst Compositions; V. Regeneration; VI. Mechanism of the Oxidation Reactions; VII. Mechanism of the Oxidation via Silver Nitrate; References; bankruptcy four. The Poisoning of steel Catalysts I. Catalysts vulnerable to PoisoningII. vital varieties of Catalyst Poisons; III. the shape of Catalyst Poisoning Curves; IV. extra elements Influencing Toxicity; V. priceless Poisoning; References; bankruptcy five. Catalytic Cracking of natural Hydrocarbons; I. advent; II. Catalytic Cracking Reactions; III. Catalytic Cracking of Paraffins; IV. Catalytic Cracking of Olefins; V. Catalytic Cracking of Naphthenes; VI. Catalytic Cracking of fragrant Hydrocarbons; VII. constitution of Cracking Catalysts; References; bankruptcy 6. Chemical features and constitution of Cracking Catalysts I. IntroductionII. size of the "Acidity" of Cracking Catalysts; III. id of the Acid facilities because the Catalytically energetic websites; IV. constitution of the Acid; V. Mechanism of Hydrocarbon Reactions on a Cracking Catalyst; References; bankruptcy 7. response charges and Selectivity in Catalyst Pores; I. creation; III . The actual photo of the Pore constitution; III. Mechanism of delivery in Catalyst Pores; IV. actual elements selecting response premiums on Porous Catalysts . (Definition of fee Constants, the elemental Differential Equation and the legislation of Conservation of Mass V. response charges in unmarried PoresVI. response premiums on useful Catalyst Pellets; VII. response premiums on Poisoned Catalysts (Apparent Selective Poisoning); VIII. impact of Pore constitution on Catalyst Selectivity; Appendix; word list of Symbols; References; bankruptcy eight. Nickel Sulfide Catalysts; I. creation; II. The Nickel-Sulfur Equilibrium; III. actual Adsorption of Gases on Ni2S2 Catalysts; IV. Chemisorption of Gases on Ni2S2; V. helps for Stabilizing Nickel Sulfide; VI. guidance of Nickel Sulfide Catalysts; VII. worthy existence and Regeneration
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8. Balandin, A. , Actu Physicochim. R . S. 14,243 (1941). 9. Taylor, H. , J . Am. Chem. 60, 627 (1938). 10. Zelinski, N. , Ber. 44,3121 (1911); ibid. 46,3678 (1912). 11. Kistiakowsky, G . , J . Am. Chem. 68, 137, 146 (1936). 12. Balandin, A. , and Rubinstein, A. , 2. physik. Chem. , 431 (1934). 13. Zelinski, N. , Ber. 66, 1716 (1923). 14. Zelinski, N. , and Balandin, A. , 2. physik. Chem. Al26, 267 (1926). 15. , Ber. 67, 1715 (1934). 16. Zelinski, N. , and Margolis, E. , Ber. 66, 1613 (1932). 17.

And Margolis, E. , Ber. 66, 1613 (1932). 17. Zelinski, N. , Ber. 44,2305 (1911). 18. Zelinski, N . , Ber. 67, 1066 (1924). 19. Lazier, W. , and Vaughen, J. , J . Am. Chem. 64, 3080 (1932). 20. Balandin, A. , and Brussow, J. , 2. physik. Chem. B34, 96 (1936). 21. Herington, E. F. , and Rideal, E. , Proc. Roy. (London) Al90, 289, 309 1. 2. 3. 4. (1947). 22. Long, J. , Frazer, J . C. , J. Am. Chem. 66, 1101 (1934). 23. Pease, R. , and Purdum, R. , J . A m . Chem. 47, 1435 (1925). BALANDIN’S CONTRIBUTION TO HETEROGENEOUS CATALYSIS 25 Emmett, P.

The strength used varies from about 5000 t o 20,000 gauss. For work on inorganic solids it is essential that the field be variable, so that measurements may be made a t several field strengths. The samples, which are often in powdered form, may be measured in glass tubes, a small correction being made for the diamagnetism of the glass. For a tube of 8 mm. external diameter, 12 cm. long, and a field of 8ooo gauss, the forces exerted on samples, such as are discussed later FIG. 1. Principle of the GouY method for memuring Magnetism and the Structure of Catalytically Active Solids* P.

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